نتایج جستجو برای: Thermal Kinetic Decomposition

تعداد نتایج: 391493  

ژورنال: مواد پرانرژی 2016

Determinations of lifetime for propellants require exact evaluation of thermal decomposition kinetic parameters. Thermal analysis is one of the tools for investigation of thermal decomposition reaction and its kinetic parameters. In this article, thermal decomposition process for a single-base propellant is investigated under 1, 2 and 3 K/min heating rates. Then by using Friedman isoconversiona...

ژورنال: مواد پرانرژی 2016

One of the characteristics of solid organic compounds and especially organic explosives is thermal behavior and kinetic of thermal decomposition. The activation energy, Arrhenius constant and model of solid state reaction as kinetic triplet can be obtained by study thermal decomposition kinetic in a solid state reaction. In the present work, the non-isothermal differential thermal analysis (DTA...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه تربیت مدرس 1382

‏‎the main purpose of this research was to:1.develop a coking model for thermal cracking of naphtha.2.study coke inhibition methods using different coke inhibitors.developing a coking model in naphtha cracking reactors requires a suitable model of the thermal cracking reactor based on a reliable kinetic model.to obtain reliable results all these models shall be solved simultaneously.for this pu...

This paper has been utilizing the simultaneous ThermoGravimetric analysis and Differential Scanning Calorimetry (TG–DSC) to investigate the thermal decomposition of magnesium-sodium nitrate pyrotechnic composition based HTPB resin. The thermal behaviors of different samples with various fuel-oxidizer ratio contents were determined. Decomposition kinetic was investigated by evaluating the in...

Journal: :iranian journal of chemistry and chemical engineering (ijcce) 2013
dunjia wang yanfang kang lianying lu

a complex of cu(ii) with 1-(6-hydroxynaphthalen-2-yl) butane-1,3-dione (hnbd) was synthesized and characterized by elemental analysis, ir, uv and dta-tg-dtg techniques.    ir spectra as well as uv-visible absorption measurements indicated that cu(ii) ion was coordinated to the hnbd ligand. the tg-dta-dtg curves showed that thermal decomposition of the anhydrous complex was a two-stage process a...

2001
K. Celis I. Van Driessche R. Mouton G. Vanhoyland S. Hoste

The thermal and kinetic aspects of solid state decomposition reactions can be complex and posses a large number of parameters to investigate. The determination of the activation energies for the several intermediates in the thermal decomposition is particularly sensitive to the overlap in thermal decomposition traces. To overcome this problem we have undertaken the detailed kinetic analysis of ...

Journal: :Physical chemistry chemical physics : PCCP 2017
Nikita V Muravyev Nobuyoshi Koga Dmitry B Meerov Alla N Pivkina

This study focused on kinetic modeling of a specific type of multistep heterogeneous reaction comprising exothermic and endothermic reaction steps, as exemplified by the practical kinetic analysis of the experimental kinetic curves for the thermal decomposition of molten ammonium dinitramide (ADN). It is known that the thermal decomposition of ADN occurs as a consecutive two step mass-loss proc...

ژورنال: مواد پرانرژی 2018

In this research, the thermal stability and decomposition kinetics of pentaerythritol tetranitrate (PETN) and Pentastite explosives have been studied experimentally using non-isothermal differential thermal analysis (DTA) and thermo-gravimetric (TG) methods at heating rates of 4.0, 6.0, 8.0 and 10.0 °C/min. The kinetic parameter of activation energy (Ea) and critical ignition temperature fo...

2016
María A. Garrido Rafael Font Juan A. Conesa

7 Abstract 8 A systematic investigation of the thermal decomposition of viscoelastic memory 9 foam (VMF) was performed using thermogravimetric analysis (TGA) to obtain the 10 kinetic parameters, and thermogravimetric analysis coupled to Fourier Transformed 11 Infrared Spectrometry (TGA-FTIR) and thermogravimetric analysis coupled to Mass 12 Spectrometry (TGA-MS) to obtain detailed information o...

ژورنال: مواد پرانرژی 2014

Determine the lifetime of explosive chemicals is one of the important research fields in recent years. Among the various methods of estimating life expectancy, methods based on solid-state kinetic analysis of the thermal decomposition of a chemical explosive are scientific and the accuracy of the method is confirmed. In this study, the determination of kinetic parameters of Ocfol explosive was ...

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